13.3 Membrane separations

Membrane separations are a crucial part of many industrial processes, from water treatment to food production. These techniques use special barriers to separate molecules based on size, charge, or other properties, allowing for efficient purification and concentration of various substances.

Understanding membrane separations is key to grasping modern separation processes. We'll explore different types of membrane filtration, from reverse osmosis to pervaporation, and examine how factors like selectivity, flux, and concentration polarization affect their performance in real-world applications.

Membrane Filtration Processes

Pressure-Driven Membrane Processes

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Top images from around the web for Pressure-Driven Membrane Processes

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• Reverse osmosis applies high pressure to overcome osmotic pressure and force solvent through a semi-permeable membrane, retaining solute on the pressurized side (desalination of seawater)
• Ultrafiltration uses pressure to force liquid through a semi-permeable membrane with pore sizes from 0.01 to 0.1 micron, retaining macromolecules and colloids (protein concentration, wastewater treatment)
• Microfiltration employs membranes with pore sizes from 0.1 to 10 microns to separate suspended particles from a liquid under pressure (clarification of wine and beer, sterile filtration)
• Nanofiltration operates at lower pressures than reverse osmosis but higher than ultrafiltration, retaining molecules with sizes in the nanometer range (water softening, removal of pesticides and herbicides)

Concentration-Driven Membrane Process

• Pervaporation combines permeation and evaporation, using a dense non-porous membrane to separate liquid mixtures based on the preferential sorption and diffusion of one component (removal of volatile organic compounds from water, dehydration of organic solvents)

Membrane Performance Characteristics

Selectivity and Flux

• Membrane selectivity measures the ability of a membrane to separate components, often expressed as the ratio of permeabilities or concentrations of components in the permeate and feed streams
• Flux represents the volumetric flow rate of fluid passing through the membrane per unit area, influenced by pressure difference, concentration gradient, and membrane resistance

Concentration Polarization and Osmotic Pressure

• Concentration polarization occurs when retained solute accumulates near the membrane surface, forming a concentration gradient that reduces the effective driving force and limits flux (fouling of reverse osmosis membranes)
• Osmotic pressure arises from the difference in solute concentrations across a semi-permeable membrane, opposing the applied pressure and reducing the effective driving force in pressure-driven processes (limiting factor in high-salinity water desalination)